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1

Organoboranes for synthesis. 6. : A convenient, general synthesis of alkylhydroperoxides via autoxidation of organoboranes

Herbert C. Brown, M.Mark Midland

Journal:

Year:

1987

Language:

english

File:

PDF, 1.04 MB

english, 1987

2

Organische Synthesen durch Verdrängung freier Radikale aus Organoboranen

Prof. Dr. Herbert C. Brown, M. Mark Midland

Journal:

Angewandte Chemie

Year:

1972

Language:

german

File:

PDF, 782 KB

german, 1972

3

Organoboranes for synthesis. 5: Stoichiometrically controlled reaction of organoboranes with oxygen under mild conditions to achieve quantitative conversion to alcohols

Herbert C. Brown, M. Mark Midland, George W. Kabalka

Journal:

Year:

1986

Language:

english

File:

PDF, 722 KB

english, 1986

4

Reduction of .alpha.,.beta.-acetylenic ketones with B-3-pinanyl-9-borabicyclo[3.3.1]nonane. High asymmetric induction in aliphatic systems

Midland, M. Mark, McDowell, Deborah C., Hatch, Robert L., Tramontano, Alfonso

Journal:

Journal of the American Chemical Society

Year:

1980

Language:

english

File:

PDF, 425 KB

english, 1980

5

Convenient general synthesis of alkyl hydroperoxides via autoxidation of organoboranes

Brown, Herbert C., Midland, M. Mark

Journal:

Journal of the American Chemical Society

Year:

1971

Language:

english

File:

PDF, 419 KB

english, 1971

6

Chiral trialkylborane reducing agents. Preparation of 1-deuterio primary alcohols of high enantiomeric purity

Midland, M. Mark, Greer, Sue, Tramontano, Alfonso, Zderic, Stephen A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 532 KB

english, 1979

7

Initiation rates for autoxidation of trialkylboranes. Effect of a steric factor on the initiation rate

Brown, Herbert C., Midland, M. Mark

Journal:

Journal of the Chemical Society D Chemical Communications

Year:

1971

Language:

english

File:

PDF, 194 KB

english, 1971

8

The Stable Pentamethylcyclopentadienyl Cation Remains Unknown

Michael Otto, David Scheschkewitz, Tsuyoshi Kato, Mark M. Midland, Joseph B. Lambert, Guy Bertrand

Journal:

Angewandte Chemie

Year:

2002

Language:

english

File:

PDF, 65 KB

english, 2002

9

The Stable Pentamethylcyclopentadienyl Cation Remains Unknown

Michael Otto, David Scheschkewitz, Tsuyoshi Kato, Mark M. Midland, Joseph B. Lambert, Guy Bertrand

Journal:

Angewandte Chemie International Edition

Year:

2002

Language:

english

File:

PDF, 64 KB

english, 2002

10

Organic Syntheses via Free-Radical Displacement Reactions of Organoboranes

Prof. Herbert C. Brown, M. Mark Midland

Journal:

Angewandte Chemie International Edition

Year:

1972

Language:

english

File:

PDF, 770 KB

english, 1972

11

Vitamin D: Structure-function analyses and the design of analogs

William H. Okamura, J. Antonio Palenzuela, Joaquin Plumet, M. Mark Midland

Journal:

Journal of Cellular Biochemistry

Year:

1992

Language:

english

File:

PDF, 736 KB

english, 1992

12

The synthesis of naturally occurring 4-alkyl- and 4-alkenyl-γ-lactones using the asymmetric reducing agent B-3-pinanyl-9-borabicyclo[3.3.1]nonane

M.Mark Midland, Alfonso Tramontano

Journal:

Tetrahedron Letters

Year:

1980

Language:

english

File:

PDF, 255 KB

english, 1980

13

Olefin-alkyl group exchange of B-alkyl-9-borabicyclo-[3.3.1]nonanes. Evidence for a dehydroboration-hydroboration process

M. Mark Midland, Janet E. Petre, Stephen A. Zderic

Journal:

Journal of Organometallic Chemistry

Year:

1979

Language:

english

File:

PDF, 273 KB

english, 1979

14

The reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with aldehydes and ketones. A facile elimination of the alkyl group by aldehydes

M.Mark Midland, Alfonso Tramontano, Stephen A. Zderic

Journal:

Journal of Organometallic Chemistry

Year:

1978

Language:

english

File:

PDF, 665 KB

english, 1978

15

Stereochemistry of the allene in the conversion of ethynylalkanol acetates into allenes via organoboranes

M.Mark Midland, Deborah C. McDowell

Journal:

Journal of Organometallic Chemistry

Year:

1978

Language:

english

File:

PDF, 204 KB

english, 1978

16

The facile reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with benzaldehyde

M.Mark Midland, Alfonso Tramontano, Stephen A Zderic

Journal:

Journal of Organometallic Chemistry

Year:

1977

Language:

english

File:

PDF, 196 KB

english, 1977

17

Asymmetric reductions of propargyl ketones : An effective approach to the synthesis of optically-active compounds

M. Mark midland, Alfonso tramontano, Aleksander kazubski, Richard S. graham, David J.S. tsai, Daniel B. cardin

Journal:

Year:

1984

Language:

english

File:

PDF, 1.46 MB

english, 1984

18

Organoboranes for synthesis : Reaction of organoboranes with representative organic azides. A general stereospecific synthesis of secondary amines and N-substituted aziridines

Herbert C. Brown, M.Mark Midland, Alan B. Levy, H.C. Brown, R.B. Wetherill, Akira Suzuki, Sunao Sono, Mitsuomi Itoh

Journal:

Year:

1987

Language:

english

File:

PDF, 861 KB

english, 1987

19

Stereocontrolled synthesis of steroid side chains via organoboranes. Stereospecific synthesis of 20R- and 20S-25-hydroxycholesterol.

M.Mark Midland, Young C. Kwon

Journal:

Tetrahedron Letters

Year:

1982

Language:

english

File:

PDF, 232 KB

english, 1982

20

Studies on Chirality Transfer in the [2,3] Sigmatropic Rearrangement of Anions Derived from Trialkylstannylmethyl Allylic Ethers. Stereospecific Synthesis of (2R)-3-Benzyloxy-2-methylpropanol.

M.Mark Midland, Young C. Kwon

Journal:

Tetrahedron Letters

Year:

1985

Language:

english

File:

PDF, 200 KB

english, 1985

21

Stereospecific synthesis of hydroxylated steroid side chains. Synthesis of 25,28-dihydroxy-7,8-dihydroergosterol and its c-24 epimer via [2,3] sigmatropic rearrangement.

M.Mark Midland, Young C. Kwon

Journal:

Tetrahedron Letters

Year:

1985

Language:

english

File:

PDF, 205 KB

english, 1985

22

Stereospecific synthesis of (25)-26-hydroxycholesterol VIA [2, 3] sigmatropic rearrangement. A new stereoselective two-carbon homologation of 20-keto steroids to the 23-aldehyde.

M.Mark Midland, Young C. Kwon

Journal:

Tetrahedron Letters

Year:

1985

Language:

english

File:

PDF, 198 KB

english, 1985

23

Stereocontrolled synthesis of 22-hydroxy-23-acetylenic steroids, key intermediates in steroid side chain construction. Observation of a directive effect by an α-chiral site during asymmetric reduction with -B-3-pinanyl-9-BBN (Alpine-Borane)

M.Mark Midland, Young C. Kwon

Journal:

Tetrahedron Letters

Year:

1984

Language:

english

File:

PDF, 230 KB

english, 1984

24

The isomerization of optically-active propargyl alcohols to terminal acetylenes.

M.Mark Midland, Ronald L. Halterman, Charles A. Brown, Angela Yamaichi

Journal:

Tetrahedron Letters

Year:

1981

Language:

english

File:

PDF, 137 KB

english, 1981

25

Temperature dependence of (+)-catechin pyran ring proton coupling constants as measured by NMR and modeled using GMMX search methodology

Fred L. Tobiason, Stephen S. Kelley, M.Mark Midland, Richard W. Hemingway

Journal:

Tetrahedron Letters

Year:

1997

Language:

english

File:

PDF, 265 KB

english, 1997

26

Effect of C2O stereochemistry on the conformational profile of the side chains of vitamin D analogs.

M.Mark Midland, Joaquin Plumet, William H. Okamura

Journal:

Bioorganic & Medicinal Chemistry Letters

Year:

1993

Language:

english

File:

PDF, 416 KB

english, 1993

27

A rapid and efficient cycloaddition of simple imines with activated dienes leading to amino sugars; Unusually high “chelation-controlled” diastereoselectivity in the addition to an α,β-dihydroxy imine protected as a ketal.

M.Mark Midland, Jim I. McLoughlin

Journal:

Tetrahedron Letters

Year:

1988

Language:

english

File:

PDF, 260 KB

english, 1988

28

Reaction of alkyl- and aryldichloroboranes with ethyl diazoacetate at low temperature

Hooz, John, Bridson, John N., Calzada, Jose G., Brown, Herbert C., Midland, M. Mark, Levy, Alan B.

Journal:

Journal of Organic Chemistry

Year:

1973

Language:

english

File:

PDF, 453 KB

english, 1973

29

A setup for bulb-to-bulb distillation

Midland, M. Mark

Journal:

Journal of Chemical Education

Year:

1993

Language:

english

File:

PDF, 414 KB

english, 1993

30

Diastereoselection in the Lewis acid catalyzed cycloaddition reaction of .alpha.-alkoxy imines

Midland, M. Mark, Koops, Roger W.

Journal:

Journal of Organic Chemistry

Year:

1992

Language:

english

File:

PDF, 576 KB

english, 1992

31

Stereoselective syntheses of erythro- and threo-.beta.-amino alcohol derivatives via hetero-Diels-Alder reactions

Afonso, Maria M., Midland, M. Mark

Journal:

Journal of the American Chemical Society

Year:

1989

Language:

english

File:

PDF, 538 KB

english, 1989

32

Synthesis of (-)-talaromycin A

Midland, M. Mark, Gabriel, Josef

Journal:

Journal of Organic Chemistry

Year:

1985

Language:

english

File:

PDF, 257 KB

english, 1985

33

Efficient asymmetric reduction of acyl cyanides with B-3-pinanyl 9-BBN (Alpine-borane)

Midland, M. Mark, Lee, Penny E.

Journal:

Journal of Organic Chemistry

Year:

1985

Language:

english

File:

PDF, 423 KB

english, 1985

34

Asymmetric synthesis of .gamma.-lactones. A facile synthesis of the sex pheromone of the Japanese beetle

Midland, M. Mark, Nhan H. Nguyen,

Journal:

Journal of Organic Chemistry

Year:

1981

Language:

english

File:

PDF, 296 KB

english, 1981

35

Biochemical Significance of the 6-s-cis Conformation of the Steroid Hormone lα,25-Dihydroxyvitamin D3 Based on the Provitamin D Skeleton

WILLIAM H. OKAMURA, M. MARK MIDLAND, ANTHONY W. NORMAN, MARION W. HAMMOND, MURRAY C. DORMANEN, ILKA NEMERE

Journal:

Annals of the New York Academy of Sciences

Year:

1995

Language:

english

File:

PDF, 197 KB

english, 1995

36

Chemistry and conformation of vitamin D molecules

Okamura, William H., Midland, M.Mark, Hammond, Marion W., Abd.Rahman, Noorsaadah, Dormanen, Murray C., Nemere, Ilka, Norman, Anthony W.

Journal:

The Journal of Steroid Biochemistry and Molecular Biology

Year:

1995

Language:

english

File:

PDF, 897 KB

english, 1995

37

Stereochemistry of hydroboration of .alpha.-chiral olefins and reduction of .alpha.-chiral ketones. An unusual anti-Cram selectivity with dialkylboranes

Midland, M. Mark, Kwon, Young C.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 415 KB

english, 1983

38

Reaction of representative organic azides with triethylborane. New route to secondary amines

Brown, Herbert C., Suzui, Akira, Sonao, Sunao, Itoh, Mitsuomi, Midland, M. Mark

Journal:

Journal of the American Chemical Society

Year:

1971

Language:

english

File:

PDF, 260 KB

english, 1971

39

Facile reaction of dialkylchloroboranes with organic azides. Remarkable enhancement of reactivity relative to trialkylboranes

Brown, Herbert C., Midland, M. Mark, Levy, Alan B.

Journal:

Journal of the American Chemical Society

Year:

1972

Language:

english

File:

PDF, 272 KB

english, 1972

40

Facile reaction of alkyl- and aryldichloroboranes with organic azides. General stereospecific synthesis of secondary amines

Brown, Herbert C., Midland, M. Mark., Levy, Alan B.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 402 KB

english, 1973

41

Two novel reactions of monomeric formaldehyde with trialkylboranes. Remarkably rapid elimination diverted by oxygen to a free-radical chain addition

Miyaura, Norio, Itoh, Mitsuomi, Suzuki, Akira, Brown, Herbert Charles, Midland, M. Mark, Jacob, Peyton

Journal:

Journal of the American Chemical Society

Year:

1972

Language:

english

File:

PDF, 262 KB

english, 1972

42

Asymmetric reductions with organoborane reagents

Midland, M. Mark

Journal:

Chemical Reviews

Year:

1989

Language:

english

File:

PDF, 1.76 MB

english, 1989

43

Kinetics of reductions of substituted benzaldehydes with B-alkyl-9-borabicyclo[3.3.1]nonane (9-BBN)

Midland, M. Mark, Zderic, Stephen A.

Journal:

Journal of the American Chemical Society

Year:

1982

Language:

english

File:

PDF, 486 KB

english, 1982

44

Stereocontrolled synthesis of a steroid side chain

Midland, M. Mark, Kwon, Young C.

Journal:

Journal of Organic Chemistry

Year:

1981

Language:

english

File:

PDF, 227 KB

english, 1981

45

Synthesis and Conformational Analysis of 1,2:3,4-Di-O-isopropylidene-alpha-D-galactopyranose: A Nuclear Magnetic Resonance and Molecular Modeling Experiment

Midland, M. Mark, Beck, John J., Peters, John L., Rennels, Roger A., Asirwatham, Gitanjali

Journal:

Journal of Chemical Education

Year:

1994

Language:

english

File:

PDF, 1.97 MB

english, 1994

46

Synthesis of alkyl 4-hydroxy-2-alkynoates

Midland, M. Mark, Tramontano, Alfonso, Cable, John R.

Journal:

Journal of Organic Chemistry

Year:

1980

Language:

english

File:

PDF, 266 KB

english, 1980

47

Asymmetric hetero Diels-Alder reaction of .alpha.-alkoxy aldehydes with activated dienes. The scope of Lewis acid chelation-controlled cycloadditions

Midland, M. Mark, Koops, Roger W.

Journal:

Journal of Organic Chemistry

Year:

1990

Language:

english

File:

PDF, 1.14 MB

english, 1990

48

Encyclopedia of Reagents for Organic Synthesis || Ethyl Lithiopropiolate

Midland, M. Mark

Year:

2001

Language:

english

File:

PDF, 42 KB

english, 2001

49

Encyclopedia of Reagents for Organic Synthesis || Ethynylmagnesium Bromide

Midland, M. Mark

Year:

2001

Language:

english

File:

PDF, 37 KB

english, 2001

50

Encyclopedia of Reagents for Organic Synthesis || Lithium Acetylide

Midland, M. Mark

Year:

2001

Language:

english

File:

PDF, 66 KB

english, 2001

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